Enhanced manganese content in Mn-MCM-41 mesoporous silicas

J. El Haskouri, S. Cabrera, A. Beltran, C. Guillem, D. Beltran, J. Latorre, M. D. Marcos, P. Amoros

Research output: Contribution to journalConference articlepeer-review

Abstract

The use of triethanolamine containing complexes of Si and Mn as hydrolytic precursors allows the synthesis of doped mesoporous silicas in which the Mn content can be modulated up to reach a minimum value of the Si/Mn molar ratio of 3. This limit value corresponds to a Mn relative content significantly higher than those reported to date for similar materials (Si/Mn = 6). According to XRD, TEM and porosity data, the mesoporous nature typical of the MCM-41 silicas is retained even for the samples having the highest Mn content.

Original languageEnglish
Pages (from-to)65-69
Number of pages5
JournalJournal De Physique. IV : JP
Volume123
DOIs
StatePublished - 2004
EventREMCES IX: 9th International Seminar on the Physical Chemistry of Solid State Materials - Agadir, Morocco
Duration: 30 Oct 20021 Nov 2002

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