Bolivianine, a new sesterpene with an unusual skeleton from Hedyosmum angustifolium, and its isomer, isobolivianine

Lucia Acebey; Michel Sauvain; Stephan Beck; Claude Moulis; Aberto Gimenez; Valérie Jullian

doi:10.1021/ol7015725

Bolivianine, a new sesterpene with an unusual skeleton from Hedyosmum angustifolium, and its isomer, isobolivianine

Lucia Acebey, Michel Sauvain, Stephan Beck, Claude Moulis, Aberto Gimenez, Valérie Jullian

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

(Chemical Equation Presented) Bolivianine, a novel sesterpene with an unprecedented skeleton, has been isolated from the trunk bark of Hedyosmum angustifolium (Chloranthaceae), with isobolivianine, an isomer formed under acidic conditions. The structure and relative stereochemistry were elucidated on the basis of spectroscopic data. A hypothesis for biogenesis was made.

Original language	English
Pages (from-to)	4693-4696
Number of pages	4
Journal	Organic Letters
Volume	9
Issue number	23
DOIs	https://doi.org/10.1021/ol7015725
State	Published - 8 Nov 2007

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abstract = "(Chemical Equation Presented) Bolivianine, a novel sesterpene with an unprecedented skeleton, has been isolated from the trunk bark of Hedyosmum angustifolium (Chloranthaceae), with isobolivianine, an isomer formed under acidic conditions. The structure and relative stereochemistry were elucidated on the basis of spectroscopic data. A hypothesis for biogenesis was made.",

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AU - Acebey, Lucia

AU - Sauvain, Michel

AU - Beck, Stephan

AU - Moulis, Claude

AU - Gimenez, Aberto

AU - Jullian, Valérie

PY - 2007/11/8

Y1 - 2007/11/8

N2 - (Chemical Equation Presented) Bolivianine, a novel sesterpene with an unprecedented skeleton, has been isolated from the trunk bark of Hedyosmum angustifolium (Chloranthaceae), with isobolivianine, an isomer formed under acidic conditions. The structure and relative stereochemistry were elucidated on the basis of spectroscopic data. A hypothesis for biogenesis was made.

AB - (Chemical Equation Presented) Bolivianine, a novel sesterpene with an unprecedented skeleton, has been isolated from the trunk bark of Hedyosmum angustifolium (Chloranthaceae), with isobolivianine, an isomer formed under acidic conditions. The structure and relative stereochemistry were elucidated on the basis of spectroscopic data. A hypothesis for biogenesis was made.

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ER -

Bolivianine, a new sesterpene with an unusual skeleton from Hedyosmum angustifolium, and its isomer, isobolivianine

Abstract

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