Biomass burning and urban emission impacts in the Andes Cordillera region based on in situ measurements from the Chacaltaya observatory, Bolivia (5240a.s.l.)

Aurelien Chauvigne, Diego Aliaga, Karine Sellegri, Nadege Montoux, Radovan Krejci, Grisa Mocnik, Isabel Moreno, Thomas Müller, Marco Pandolfi, Fernando Velarde, Kay Weinhold, Patrick Ginot, Alfred Wiedensohler, Marcos Andrade, Paolo Laj

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Abstract

This study documents and analyses a 4-year continuous record of aerosol optical properties measured at the Global Atmosphere Watch (GAW) station of Chacaltaya (CHC; 5240a.s.l.), in Bolivia. Records of particle light scattering and particle light absorption coefficients are used to investigate how the high Andean Cordillera is affected by both long-range transport and by the fast-growing agglomeration of La Paz-El Alto, located approximately 20km away and 1.5km below the sampling site. The extended multi-year record allows us to study the properties of aerosol particles for different air mass types, during wet and dry seasons, also covering periods when the site was affected by biomass burning in the Bolivian lowlands and the Amazon Basin. The absorption, scattering, and extinction coefficients (median annual values of 0.74, 12.14, and 12.96Mm<span classCombining double low line"inline-formula">-1</span> respectively) show a clear seasonal variation with low values during the wet season (0.57, 7.94, and 8.68Mm<span classCombining double low line"inline-formula">-1</span> respectively) and higher values during the dry season (0.80, 11.23, and 14.51Mm<span classCombining double low line"inline-formula">-1</span> respectively). The record is driven by variability at both seasonal and diurnal scales. At a diurnal scale, all records of intensive and extensive aerosol properties show a pronounced variation (daytime maximum, night-time minimum), as a result of the dynamic and convective effects. The particle light absorption, scattering, and extinction coefficients are on average 1.94, 1.49, and 1.55 times higher respectively in the turbulent thermally driven conditions than the more stable conditions, due to more efficient transport from the boundary layer. Retrieved intensive optical properties are significantly different from one season to the other, reflecting the changing aerosol emission sources of aerosol at a larger scale. Using the wavelength dependence of aerosol particle optical properties, we discriminated between contributions from natural (mainly mineral dust) and anthropogenic (mainly biomass burning and urban transport or industries) emissions according to seasons and local circulation. The main sources influencing measurements at CHC are from the urban area of La Paz-El Alto in the Altiplano and from regional biomass burning in the Amazon Basin. Results<span idCombining double low line"page14806"/> show a 28% to 80% increase in the extinction coefficients during the biomass burning season with respect to the dry season, which is observed in both tropospheric dynamic conditions. From this analysis, long-term observations at CHC provide the first direct evidence of the impact of biomass burning emissions of the Amazon Basin and urban emissions from the La Paz area on atmospheric optical properties at a remote site all the way to the free troposphere.

Original languageEnglish
Pages (from-to)14805-14824
Number of pages20
JournalAtmospheric Chemistry and Physics
Volume19
Issue number23
DOIs
StatePublished - 10 Dec 2019

Bibliographical note

Funding Information:
We acknowledge the financial support from IRD (Institut de Recherche pour le Developpement under the Jeune Equipe programme CHARME awarded to LFA, by Labex

Funding Information:
Acknowledgements. We acknowledge the financial support from IRD (Institut de Recherche pour le Développement) under the Jeune Equipe programme CHARME awarded to LFA, by Labex OSUG@2020 (Investissements d’avenir – ANR10 LABX56) and by ACTRIS-France National Research infrastructure. We gratefully acknowledge Souichiro Hioki for his help with English corrections and proofreading of an earlier version of this paper.

Funding Information:
Financial support. This research has been supported by Euro-

Funding Information:
pean Union (grant agreement no. 654109) under the ACTRIS-2 (Aerosols, Clouds, and Trace gases Research InfraStructure) project.

Publisher Copyright:
© Author(s) 2019.

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