Alkaloids from Brunsvigia orientalis

Francesc Viladomat; Giovanna Rocio Almanza Vega Almanza Vega; Carles Codina; Jaume Bastida; William E. Campbell; Shaheed Mathee

doi:10.1016/S0031-9422(96)00506-7

Alkaloids from Brunsvigia orientalis

Francesc Viladomat, Giovanna Rocio Almanza Vega Almanza Vega, Carles Codina, Jaume Bastida, William E. Campbell, Shaheed Mathee

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Twelve alkaloids have been isolated from bulbs of Brunsvigia orientalis. 1-Epibowdensine, 1-epidemethoxybowdensine and 1-epidecacetylbowdensine are reported here for the first time. The structure and stereochemistry of these new alkaloids have been determined by physical and spectroscopic methods. The ¹H and ¹³C NMR spectra of 6-hydroxycrinamine (both epimers) and crinamidine were completely assigned by means of 2D NMR techniques.

Original language	English
Pages (from-to)	1379-1384
Number of pages	6
Journal	Phytochemistry
Volume	43
Issue number	6
DOIs	https://doi.org/10.1016/S0031-9422(96)00506-7
State	Published - Dec 1996
Externally published	Yes

Bibliographical note

Funding Information:
Universitats i Recerca, Generalitat de Catalunya. W.E.C. and S.M. thank the University of Cape Town for financial support. Thanks are also due to M. Viviers for the collection and authentication of plant material. G.R.A. thanks the Instituto de Cooperaci6n Ibero-americana for the provision of a research fellowship.

Funding Information:
Acknowledgements--Part of this work was supported financially by CICYT and the Comissionat per a

Keywords

1- epibowdensine
1-epideacetylbowdensine
1-epidemethoxybowdensine
6-hydroxy-crinamine
alkaloids
Amaryllidaceae
Brunsvigia orientalis
bulbs
buphan idrine
buphanisine
crinamidine
crinamine
crinine
epibuphanisine
lycorine
undulatine

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10.1016/S0031-9422(96)00506-7

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title = "Alkaloids from Brunsvigia orientalis",

abstract = "Twelve alkaloids have been isolated from bulbs of Brunsvigia orientalis. 1-Epibowdensine, 1-epidemethoxybowdensine and 1-epidecacetylbowdensine are reported here for the first time. The structure and stereochemistry of these new alkaloids have been determined by physical and spectroscopic methods. The 1H and 13C NMR spectra of 6-hydroxycrinamine (both epimers) and crinamidine were completely assigned by means of 2D NMR techniques.",

keywords = "1- epibowdensine, 1-epideacetylbowdensine, 1-epidemethoxybowdensine, 6-hydroxy-crinamine, alkaloids, Amaryllidaceae, Brunsvigia orientalis, bulbs, buphan idrine, buphanisine, crinamidine, crinamine, crinine, epibuphanisine, lycorine, undulatine",

author = "Francesc Viladomat and {Almanza Vega}, {Giovanna Rocio Almanza Vega} and Carles Codina and Jaume Bastida and Campbell, {William E.} and Shaheed Mathee",

note = "Funding Information: Universitats i Recerca, Generalitat de Catalunya. W.E.C. and S.M. thank the University of Cape Town for financial support. Thanks are also due to M. Viviers for the collection and authentication of plant material. G.R.A. thanks the Instituto de Cooperaci6n Ibero-americana for the provision of a research fellowship. Funding Information: Acknowledgements--Part of this work was supported financially by CICYT and the Comissionat per a",

year = "1996",

month = dec,

doi = "10.1016/S0031-9422(96)00506-7",

language = "Ingl{\'e}s",

volume = "43",

pages = "1379--1384",

journal = "Phytochemistry",

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T1 - Alkaloids from Brunsvigia orientalis

AU - Viladomat, Francesc

AU - Almanza Vega, Giovanna Rocio Almanza Vega

AU - Codina, Carles

AU - Bastida, Jaume

AU - Campbell, William E.

AU - Mathee, Shaheed

N1 - Funding Information: Universitats i Recerca, Generalitat de Catalunya. W.E.C. and S.M. thank the University of Cape Town for financial support. Thanks are also due to M. Viviers for the collection and authentication of plant material. G.R.A. thanks the Instituto de Cooperaci6n Ibero-americana for the provision of a research fellowship. Funding Information: Acknowledgements--Part of this work was supported financially by CICYT and the Comissionat per a

PY - 1996/12

Y1 - 1996/12

N2 - Twelve alkaloids have been isolated from bulbs of Brunsvigia orientalis. 1-Epibowdensine, 1-epidemethoxybowdensine and 1-epidecacetylbowdensine are reported here for the first time. The structure and stereochemistry of these new alkaloids have been determined by physical and spectroscopic methods. The 1H and 13C NMR spectra of 6-hydroxycrinamine (both epimers) and crinamidine were completely assigned by means of 2D NMR techniques.

AB - Twelve alkaloids have been isolated from bulbs of Brunsvigia orientalis. 1-Epibowdensine, 1-epidemethoxybowdensine and 1-epidecacetylbowdensine are reported here for the first time. The structure and stereochemistry of these new alkaloids have been determined by physical and spectroscopic methods. The 1H and 13C NMR spectra of 6-hydroxycrinamine (both epimers) and crinamidine were completely assigned by means of 2D NMR techniques.

KW - 1- epibowdensine

KW - 1-epideacetylbowdensine

KW - 1-epidemethoxybowdensine

KW - 6-hydroxy-crinamine

KW - alkaloids

KW - Amaryllidaceae

KW - Brunsvigia orientalis

KW - bulbs

KW - buphan idrine

KW - buphanisine

KW - crinamidine

KW - crinamine

KW - crinine

KW - epibuphanisine

KW - lycorine

KW - undulatine

UR - http://www.scopus.com/inward/record.url?scp=0030484345&partnerID=8YFLogxK

U2 - 10.1016/S0031-9422(96)00506-7

DO - 10.1016/S0031-9422(96)00506-7

M3 - Artículo

AN - SCOPUS:0030484345

VL - 43

SP - 1379

EP - 1384

JO - Phytochemistry

JF - Phytochemistry

SN - 0031-9422

IS - 6

ER -

Alkaloids from Brunsvigia orientalis

Abstract

Bibliographical note

Keywords

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